The synthesis and characterization of cycloalkoxy-linear phosphazenes

被引：12

作者：

Ozturk, AI

Aslan, F ^{[1
]}

Cil, E

Arslan, M

Kiliç, A

机构：

[1] Firat Univ, Fen Ed Fak, TR-23169 Elazig, Turkey

[2] Harran Univ, Sanliurfa, Turkey

[3] Gebze High Technol Inst, Kocaeli, Turkey

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2003年 / 178卷 / 10期

关键词：

alcoholysis; alkoxyphosphazenes; cycloalkoxyphosphazenes; linear phosphazenes; monophosphazenes;

D O I：

10.1080/713744554

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of N-dichlorophosphoryl-P-trichlorophosphazene, Cl3P=N-P(O)Cl-2 with the sodium salts of cyclopentanol, cyclohexanol, 4-methylcyclohexanol, 3-methylcyclohexanol, 3-methylcyclopentanol are discussed. Pentacycloalkoxy-substituted phosphazenes were obtained from cyclopentanol, 4-methylcyclohexanol, 3-methylcyclohexanol, 3-methylcyclopentanol. Tetrasubstituted derivative also was obtained from cyclohexanol at the same conditions. The structure of products was defined by IR, H-1, C-13, P-31 NMR, and mass spectroscopy.

引用

页码：2097 / 2105

页数：9

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