The synthesis and characterization of cycloalkoxy-linear phosphazenes

被引：12
|
作者：
Ozturk, AI
Aslan, F [1 ]
Cil, E
Arslan, M
Kiliç, A
机构：
[1] Firat Univ, Fen Ed Fak, TR-23169 Elazig, Turkey
[2] Harran Univ, Sanliurfa, Turkey
[3] Gebze High Technol Inst, Kocaeli, Turkey
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2003年 / 178卷 / 10期
关键词：
alcoholysis; alkoxyphosphazenes; cycloalkoxyphosphazenes; linear phosphazenes; monophosphazenes;
D O I：
10.1080/713744554
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of N-dichlorophosphoryl-P-trichlorophosphazene, Cl3P=N-P(O)Cl-2 with the sodium salts of cyclopentanol, cyclohexanol, 4-methylcyclohexanol, 3-methylcyclohexanol, 3-methylcyclopentanol are discussed. Pentacycloalkoxy-substituted phosphazenes were obtained from cyclopentanol, 4-methylcyclohexanol, 3-methylcyclohexanol, 3-methylcyclopentanol. Tetrasubstituted derivative also was obtained from cyclohexanol at the same conditions. The structure of products was defined by IR, H-1, C-13, P-31 NMR, and mass spectroscopy.
引用
收藏
页码：2097 / 2105
页数：9
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