Fluctuation dynamics of chemiluminescence in the maillard reaction

被引:2
|
作者
Lakeev, S. G. [1 ]
Voeikov, V. L. [2 ]
Timashev, S. F. [1 ]
机构
[1] Karpov Res Physicochem Inst, Moscow 105064, Russia
[2] Moscow MV Lomonosov State Univ, Moscow, Russia
关键词
General Chemistry; Maillard Reaction; Methylglyoxal; Anomalous Diffusion; Fluctuation Dynamic;
D O I
10.1134/S1070363211010403
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The general problems of information deriving from the oscillation kinetics of Belousov-Zhabotinsky reactions were discussed. The discussion was organized around a particular example of the complex fluctuation dynamics of the Maillard reaction, i.e., a multistage reaction between a carbonylcontaining compound and the nucleophilic amino group of an amino-containing compound at different temperatures, as visualized by chemiluminescence. Flicker-noise spectroscopy served as methodological background of the fluctuation analysis comprising the two main steps: separation of low-frequency components attributed to resonances and their interference, from the source signals and analysis of the remaining chaotic components. Possibility of modeling the chaotic dynamics of fluctuations of the measured dynamic variables in terms of anomalous diffusion was shown.
引用
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页码:234 / 242
页数:9
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