Relationship between structure and optical properties of lithium triborate

被引：1
|
作者：
Etxebarria, J.
Ortega, J.
Folcia, C. L.
机构：
[1] Univ Basque Country, Fac Ciencias, Dept Fis Aplicada 2, E-48080 Bilbao, Spain
[2] Univ Basque Country, Fac Ciencias, Dept Fis Mat Condensada, E-48080 Bilbao, Spain
来源：
JOURNAL OF APPLIED CRYSTALLOGRAPHY | 2007年 / 40卷
关键词：
D O I：
10.1107/S0021889807033663
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Measurements of the optical rotation of LiB3O5 have been carried out using a high-accuracy universal polarimeter in the temperature range 298-503 K. The results have been analyzed within the framework of a point-dipole model for the optical rotation. Though the magnitude of the rotation is very small, its sign has been clearly determined and linked to the crystallographic structure. A slight modification of the point-dipole model also permits an explanation of the values of the second-order susceptibility coefficients for second-harmonic generation.
引用
收藏
页码：919 / 923
页数：5
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