Asymmetric synthesis of tertiary thiols and thioethers

被引：180

作者：

Clayden, Jonathan ^{[1
]}

MacLellan, Paul ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 7卷

关键词：

asymmetric synthesis; organolithium; sulfur; substitution; thiol; OXIDATION-REDUCTION CONDENSATION; ALKYL ARYL SULFIDES; HIGHLY ENANTIOSELECTIVE REACTIONS; STEREOCHEMICAL COURSE; ALPHA-ARYLATION; CONFIGURATIONAL STABILITY; STEREOSPECIFIC SYNTHESIS; ENANTIOMERICALLY PURE; CARBOXYLIC-ACIDS; BOND FORMATION;

D O I：

10.3762/bjoc.7.68

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantiomerically pure tertiary thiols provide a major synthetic challenge, and despite the importance of chiral sulfur-containing compounds in biological and medicinal chemistry, surprisingly few effective methods are suitable for the asymmetric synthesis of tertiary thiols. This review details the most practical of the methods available.

引用

页码：582 / 595

页数：14

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