New uses of amino acids as chiral building blocks in organic synthesis

被引：16

作者：

Reetz, MT ^{[1
]}

Lee, WK ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 20期

关键词：

D O I：

10.1021/ol0164029

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] N,N-Dibenzylamino aldehydes have emerged as a highly useful class of chiral building blocks in synthetic organic chemistry. We envisioned the transformation of the N,N-dibenzylamino aldehydes to the corresponding aldimines followed by diastereoselective methylene transfer with a sulfonium ylide to obtain alpha -amino aziridines in high yields.

引用

页码：3119 / 3120

页数：2

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