Evidence for the in situ formation of copper acetylides during Pd/Cu catalyzed synthesis of enynes:: a new synthesis of allenynols

被引：27

作者：

Bertus, P

Fécourt, F

Bauder, C

Pale, P

机构：

[1] Univ Strasbourg 1, Inst Le Bel, CNRS,UMR 7123, Lab Synth & React Organ, F-67000 Strasbourg, France

[2] Univ Reims, CNRS, UMR 6519, Lab React Select & Applicat, F-51687 Reims, France

来源：

NEW JOURNAL OF CHEMISTRY | 2004年 / 28卷 / 01期

关键词：

D O I：

10.1039/b309094a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The in situ formation of copper acetylide in Pd/Cu catalyzed coupling reactions of acetylenic derivatives has been demonstrated by the reaction with ethynyloxiranes, which provides allenynols; a new Cu catalyzed route to the latter has also been found.

引用

页码：12 / 14

页数：3

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