A re-investigation of the reaction of [RuCl2(CO)(3)](2) with C5H5(Me(3)Si) X-ray structure determination of [Ru(CO)(3)(eta-C5H5)][fac-RuCl3(CO)(3)]

被引：10

作者：

Griffith, CS

Koutsantonis, GA

Raston, CL

Selegue, JP

Skelton, BW

White, AH

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT CHEM,PERTH,WA 6907,AUSTRALIA

[2] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

[3] UNIV KENTUCKY,DEPT CHEM,LEXINGTON,KY 40506

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 518卷 / 1-2期

基金：

澳大利亚研究理事会;

关键词：

ruthenium anion; carbonyl; silicon; cyclopentadienyl; starting material; superlattice symmetry; ruthenium cation;

D O I：

10.1016/0022-328X(96)06196-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [RuCl2(CO)(3)](2) with C5H5(SiMe(3)) has been re-investigated. In our hands, in refluxing tetrahydrofuran, the reaction gives consistently [Ru(CO)(3)(eta-C5H5)][fac-RuCl3(CO)(3)], 1, and [RuCl(CO)(2)(eta-C5H5)], 2, in 68% and 12% yield respectively. The reaction of CO with commercially available hydrated OsCl3 gives [OsCl2(CO)(3)](2) in 44% yield. The crystal structure of [Ru(CO)(3)(eta-C5H5)][fac-RuCl3(CO)(3)] is reported; superlattice symmetry is observed.

引用

页码：197 / 202

页数：6

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