New methacrylic imidazolium poly(ionic liquid) gel with super swelling capacity for oil-in-water emulsions

被引：5

作者：

Zhang, Xing ^{[1
]}

Wang, Shuo-Jue ^{[1
]}

Peng, Jing ^{[1
]}

Li, Jiu-Qiang ^{[1
]}

Xu, Ling ^{[2
]}

Zhai, Mao-Lin ^{[1
]}

机构：

[1] Peking Univ, Radiochem & Radiat Chem Key Lab Fundamental Sci, Coll Chem & Mol Engn,Beijing Natl Lab Mol Sci, Minist Educ,Key Lab Polymer Chem & Phys, Beijing 100871, Peoples R China

[2] Peking Univ, Dept Energy & Resources Engn, Coll Engn, Beijing 100871, Peoples R China

来源：

NUCLEAR SCIENCE AND TECHNIQUES | 2016年 / 27卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Poly(ionic liquid)s; PMEMImBr gel; Radiation cross-linking; Swelling; Emulsion; IONIC-LIQUID; BLOCK-COPOLYMERS; HYDROGELS; POLYMERS; BEHAVIOR; CONDUCTIVITY; TEMPERATURE; SOLVENTS; COLLAPSE; ACID;

D O I：

10.1007/s41365-016-0039-0

中图分类号：

TL [原子能技术]; O571 [原子核物理学];

学科分类号：

0827 ; 082701 ;

摘要：

A new polymeric ionic liquid gel was prepared with 1-[(2-methacryloyloxy)ethyl]-3-methylimidazolium bromide (MEMImBr) via radiation-induced polymerization and cross-linking at room temperature. The resultant PMEMImBr gel exhibits high strength and flexibility as well as special swelling behavior in oil-in-water (O/W) emulsions. The swelling behavior of PMEMImBr gel in emulsions is similar to that in water except that the swelling rate in emulsions is slightly smaller than that in water. The organic solvents with higher polarity in the emulsions contribute to the swelling of PMEMImBr gels, and the O/W proportion of emulsion in the swollen gel equals approximately that of original emulsion when the concentration of organic solvent is lower than 0.2 g/g.

引用

页数：10

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