The compatibilizing effect of poly(styrene-co-4-vinylpyridine) copolymers on the polystyrene-polyethylene-based ionomer blends

被引：0
|
作者：
Kim, DH
Jo, WH
Lee, SC [1 ]
Kim, HC
机构：
[1] Kumoh Natl Univ Technol, Dept Polymer Sci & Engn, Kumi 730701, South Korea
[2] Seoul Natl Univ, Dept Fiber & Polymer Sci, Seoul 151742, South Korea
[3] Hyosung T&C Co Ltd, Cent Res Inst, Anyang 430080, South Korea
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 1998年 / 69卷 / 04期
关键词：
styrene-co-4-vinylpyridine copolymers; ionomer; ion-dipole interaction; compatibilization;
D O I：
10.1002/(SICI)1097-4628(19980725)69:4<807::AID-APP20>3.0.CO;2-K
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The compatibilizing effect of styrene-co-4-vinylpyridine (SVP) random copolymers on the immiscible polystyrene (PS)-polyethylene-based ionomer (Surlyn) blends was examined by means of scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and tensile test. For the binary SVP-Surlyn and ternary PS-Surlyn-SVP blends, the domain size of dispersed phase decreases dramatically with the increase in the vinyl pyridine (VP) content of the SVP copolymers. The mechanical properties are improved with increasing the VP content in copolymers. FTIR results suggest that the compatibilization in this blend system is attributed to the ion-dipole interaction between the polar VP groups of SVP copolymer and ionic groups of Surlyn. (C) 1998 John Wiley & Sons, Inc.
引用
收藏
页码：807 / 816
页数：10
相关论文
共 50 条
  • [31] X-ray photoelectron spectroscopic studies of ionic interactions between sulfonated polystyrene and poly(styrene-co-4-vinylpyridine)
    Goh, SH
    Lee, SY
    Dai, J
    Tan, KL
    POLYMER, 1996, 37 (23) : 5305 - 5308
  • [32] OXIDATIVE CLEAVAGE OF 4-METHYLCATECHOL WITH A CU COMPLEX BOUND TO POLY(STYRENE-CO-4-VINYLPYRIDINE)
    NISHIDE, H
    MINAKATA, T
    TSUCHIDA, E
    JOURNAL OF MOLECULAR CATALYSIS, 1982, 15 (03): : 327 - 335
  • [33] Polyimide/poly(styrene-co-4-vinylpyridine) nanocomposite films as precursors for the preparation of polyimide nanofoams
    Xu, ZK
    Liu, ZM
    Xiao, L
    Dai, QW
    Kou, RQ
    JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2002, 23 (04) : 519 - 527
  • [34] POLY 115-A study of hydrogen bonding in poly(styrene-co-methacrylic acid)/poly(styrene-co-4-vinylpyridine) systems
    Djadoun, Said, Sr.
    Benabdelghani, Zitouni, Sr.
    Elmiloudi, Khaled, Sr.
    Etxeberria, Augustin, Sr.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 236
  • [35] Studies on computational chemistry and complexation behavior between Poly(styrene-co-methacrylic acid) and Poly(styrene-co-4-vinylpyridine)
    Israr, Sobia
    Israr, Fozia
    MOROCCAN JOURNAL OF CHEMISTRY, 2019, 7 (01): : 123 - 131
  • [36] Compatibilizing effects of poly(styrene-co-methacrylic acid) on immiscible blends of polystyrene and poly(ethylene glycol)
    Watanabe, N
    Akiba, I
    Akiyama, S
    EUROPEAN POLYMER JOURNAL, 2001, 37 (09) : 1837 - 1842
  • [37] Preparation of silica-coated poly(styrene-co-4-vinylpyridine) particles and hollow particles
    Zou, Hua
    Wu, Shishan
    Shen, Jian
    LANGMUIR, 2008, 24 (18) : 10453 - 10461
  • [38] Phase Behavior of binary and ternary blends of poly(styrene-co-methacrylic acid), poly(styrene-co-4-vinylpyridine), and poly(2,6-dimethyl-1,4-phenylene oxide)
    Benabdelghani, Z.
    Djadoun, S.
    Etxeberria, A.
    Iruin, J. J.
    Uriarte, C.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 108 (01) : 220 - 227
  • [39] Blends of poly(isobutyl methacrylate-co-acrylic acid) with poly{styrene-co-[2-(N,N-dimethyl amino)ethyl methacrylate]} or poly(styrene-co-4-vinylpyridine
    HadjHamou, AS
    Habi, A
    Djadoun, S
    EUROPEAN POLYMER JOURNAL, 1997, 33 (07) : 1105 - 1111
  • [40] CYANOACRYLATE-CONTAINING COPOLYMERS AS COMPATIBILIZING AGENTS FOR POLY(STYRENE-CO-ACRYLONITRILE) POLY(METHYL METHACRYLATE) BLENDS
    IVANOVA, MP
    KOTZEV, DL
    EUROPEAN POLYMER JOURNAL, 1990, 26 (02) : 189 - 190
12345