Multiple functions of amines in the synthesis of anionic, cationic, and neutral indium oxalates

被引：1
|
作者：
Zhong, Yeshuang [1 ]
Chen, Cheng [1 ]
Zhang, Chunchun [2 ]
Xu, Dingguo [1 ]
Lin, Zhien [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Chengdu 610064, Sichuan, Peoples R China
[2] Sichuan Univ, Analyt & Testing Ctr, Chengdu 610064, Sichuan, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2017年 / 84卷
关键词：
Crystal structure; Indium oxalate; Topology; Luminescence; SOLVENT-FREE SYNTHESIS; PROTON CONDUCTIVITY; METAL CARBOXYLATES; CHANNELS;
D O I：
10.1016/j.inoche.2017.08.029
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new indium oxalates, formulated as H(3)dpta center dot In(C2O4)(H2O)(3)center dot 2SO(4) (1), In(qd)(C2O4)(1.5)center dot 1.5H(2)O (2), and H(2)bpp center dot In-2(C2O4)(4) (3) in which dpta = dipropylenetriamine, qd = quinoxaline-2,3(1H,4H)-dione, and bpp = 1,3-bis(4-piperidyl)propane, were prepared in the presence of different amines. These compounds have cationic, neutral, and anionic frameworks, respectively. Topological analyses reveal that compound 2 has an hcb net, while compound 3 has a dia net. The photoluminescent property of compound 2 was also investigated. (C) 2017 Published by Elsevier B.V.
引用
收藏
页码：186 / 189
页数：4
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