Fluorescence turn-off sensing of lead and gentamicin based on phosphorus and chlorine co-doped carbon dots

被引:5
|
作者
Sefid-Sefidehkhan, Yasaman [1 ,2 ,3 ]
Jouyban, Abolghasem [1 ,2 ,4 ]
Rahimpour, Elaheh [1 ,2 ,5 ]
机构
[1] Tabriz Univ Med Sci, Pharmaceut Anal Res Ctr, Tabriz 5165665811, Iran
[2] Tabriz Univ Med Sci, Fac Pharm, Tabriz 5165665811, Iran
[3] Univ Mohaghegh Ardabili, Dept Chem, Ardebil 1313156199, Iran
[4] Near East Univ, Fac Pharm, POB 99138, Mersin 10, North Cyprus, Turkey
[5] Tabriz Univ Med Sci, Infect & Trop Dis Res Ctr, Tabriz 5165665811, Iran
关键词
Probe; Lead; Gentamicin; Carbon dots; Central composite design; SOLID-PHASE EXTRACTION; QUANTUM DOTS; IONS; PRECONCENTRATION; CADMIUM; SULFATE; SENSOR; GREEN; ACID;
D O I
10.1016/j.microc.2022.107753
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In the present study, CQDs co-doped with phosphorus and chlorine have been synthesized by a hydrothermal technique. The synthesized CQDs possess a mean size of < 20 nm and show excitation-independent features. The investigations presented that the CQD's fluorescence intensity was markedly quenched in the presence Pb2+ due to the formation of a stable non-luminescent complex that regarding this mechanism, a fluorescent platform was offered for Pb2+ ions in water samples. Furthermore, the gentamicin adding into the P, Cl-CQDs + Pb system had a more quenching effect on CQD's fluorescence and so another probe was proposed for gentamicin determina-tion. The detection limits for the proposed methods were 0.001 mu g.mL(-1) for Pb(2+)and 0.003 mu g.mL(-1) for gentamicin, respectively. The probe was successfully utilized in the environmental samples with high accuracy and selectivity.
引用
收藏
页数:8
相关论文
共 50 条
  • [31] Ultrasensitive turn-off fluorescence detection of iodide using carbon dots/gold nanocluster as fluorescent nanoprobe
    Zou, Xue
    Hu, Jie
    Zhu, Huanhuan
    Chen, Qiumeng
    Gong, Zhengjun
    MICROCHEMICAL JOURNAL, 2023, 185
  • [32] Nitrogen-doped carbon dots as a "turn-off" fluorescence probe for mercury(<sc>ii</sc>) detection and live cell imaging
    Lei, Yufei
    Li, Qi
    Li, Qian
    He, Dongxiu
    Xue, Jinhua
    Liao, Lifu
    Wang, Jikai
    Xiao, Xilin
    NEW JOURNAL OF CHEMISTRY, 2024, 48 (14) : 6246 - 6253
  • [33] Highly selective detection of epinephrine by a "turn-off" fluorescent sensor based on N-doped carbon quantum dots
    Wu, Yue
    Lan, Wei
    He, Song
    Guo, Xiaoming
    Hai, Chengying
    Zhao, Xiangyu
    Chen, Hengye
    Long, Wanjun
    She, Yuanbin
    Fu, Haiyan
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2023, 298
  • [34] Nitrogen doped carbon dots for turn-off fluorescent detection of alkaline phosphatase activity based on inner filter effect
    Zhang, Yuhua
    Nie, Yifeng
    Zhu, Ruifeng
    Han, Dong
    Zhao, Hong
    Li, Zengxi
    TALANTA, 2019, 204 : 74 - 81
  • [35] Sustainable carbon dots as "turn-off" fluorescence sensor for highly sensitive Pb2+ detection
    Ravi, Soumya
    Jayaraj, M. K.
    EMERGENT MATERIALS, 2020, 3 (01) : 51 - 56
  • [36] Fluorescent turn-off competitive immunoassay for biotin based on hydrothermally synthesized carbon dots
    Wensong Yao
    Namei Wu
    Zhen Lin
    Jinyuan Chen
    Shaoguang Li
    Shaohuang Weng
    Lingling Zhang
    Ailin Liu
    Xinhua Lin
    Microchimica Acta, 2017, 184 : 907 - 914
  • [37] Fluorescent turn-off competitive immunoassay for biotin based on hydrothermally synthesized carbon dots
    Yao, Wensong
    Wu, Namei
    Lin, Zhen
    Chen, Jinyuan
    Li, Shaoguang
    Weng, Shaohuang
    Zhang, Lingling
    Liu, Ailin
    Lin, Xinhua
    MICROCHIMICA ACTA, 2017, 184 (03) : 907 - 914
  • [38] Sustainable carbon dots as “turn-off” fluorescence sensor for highly sensitive Pb2+ detection
    Soumya Ravi
    M. K. Jayaraj
    Emergent Materials, 2020, 3 : 51 - 56
  • [39] Facile synthesis of phosphorus and nitrogen co-doped carbon dots with excellent fluorescence emission towards cellular imaging
    Cao, Fang-Jun
    Hou, Xiang
    Wang, Kai-Feng
    Jin, Tie-Zhi
    Feng, Hui
    RSC ADVANCES, 2023, 13 (30) : 21088 - 21095
  • [40] Carbon dots co-doped with nitrogen and chlorine for “off-on” fluorometric determination of the activity of acetylcholinesterase and for quantification of organophosphate pesticides
    Meiling Yang
    Mingwang Liu
    Zipeng Wu
    Yu He
    Yili Ge
    Gongwu Song
    Jiangang Zhou
    Microchimica Acta, 2019, 186