"Host-guest" interaction between cyclohexasilane and amphiphilic invertible macromolecules

被引：9

作者：

Kohut, Ananiy ^{[1
]}

Dai, Xuliang ^{[2
]}

Pinnick, Danielle ^{[2
]}

Schulz, Douglas L. ^{[2
]}

Voronov, Andriy ^{[1
]}

机构：

[1] N Dakota State Univ, Dept 2760, Dept Coatings & Polymer Mat, Fargo, ND 58108 USA

[2] N Dakota State Univ, Ctr Nanoscale Sci & Engn, Fargo, ND 58108 USA

来源：

SOFT MATTER | 2011年 / 7卷 / 08期

基金：

美国国家科学基金会;

关键词：

POLYESTERS; MICELLES;

D O I：

10.1039/c0sm01337d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Liquid cyclohexasilane (Si6H12) is localized within polymeric templates from amphiphilic invertible polymers (AIPs) to form a stable composition. NMR study reveals Si6H12 primarily interacts with ester group-containing polymeric fragments. Interaction with ether group-containing fragments occurs at higher silane concentration. AIP self-assembly gives rise to an additional interaction between cyclohexasilane and hydrophobic polymeric domains.

引用

页码：3717 / 3720

页数：4

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