"Host-guest" interaction between cyclohexasilane and amphiphilic invertible macromolecules

被引：9
|
作者：
Kohut, Ananiy [1 ]
Dai, Xuliang [2 ]
Pinnick, Danielle [2 ]
Schulz, Douglas L. [2 ]
Voronov, Andriy [1 ]
机构：
[1] N Dakota State Univ, Dept 2760, Dept Coatings & Polymer Mat, Fargo, ND 58108 USA
[2] N Dakota State Univ, Ctr Nanoscale Sci & Engn, Fargo, ND 58108 USA
来源：
SOFT MATTER | 2011年 / 7卷 / 08期
基金：
美国国家科学基金会;
关键词：
POLYESTERS; MICELLES;
D O I：
10.1039/c0sm01337d
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Liquid cyclohexasilane (Si6H12) is localized within polymeric templates from amphiphilic invertible polymers (AIPs) to form a stable composition. NMR study reveals Si6H12 primarily interacts with ester group-containing polymeric fragments. Interaction with ether group-containing fragments occurs at higher silane concentration. AIP self-assembly gives rise to an additional interaction between cyclohexasilane and hydrophobic polymeric domains.
引用
收藏
页码：3717 / 3720
页数：4
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