NiZn2(PO4)2•4H2O, a nickel-doped modification of hopeite

被引：3

作者：

Wu, WY ^{[1
]}

Liang, XQ ^{[1
]}

Li, YZ ^{[1
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S160053680501408X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Green crystals of the title compound, nickel dizinc phosphate tetrahydrate, have been prepared hydrothermally. The compound is isostructural with hopeite, Zn-3(PO4)(2)(.)4H(2)O, with nickel completely substituted for zinc at the octahedral site, resulting in [ZnPO4](-) layers bridged by cis Ni(H2O)4O(2) octahedra. O-(HO)-O-... hydrogen bonds help to stabilize the structure. The Ni atom and two water O atoms occupy special positions with mirror symmetry.

引用

页码：I108 / I110

页数：3

共 50 条

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