NiZn2(PO4)2•4H2O, a nickel-doped modification of hopeite

被引：3
|
作者：
Wu, WY [1 ]
Liang, XQ [1 ]
Li, YZ [1 ]
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词：
D O I：
10.1107/S160053680501408X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Green crystals of the title compound, nickel dizinc phosphate tetrahydrate, have been prepared hydrothermally. The compound is isostructural with hopeite, Zn-3(PO4)(2)(.)4H(2)O, with nickel completely substituted for zinc at the octahedral site, resulting in [ZnPO4](-) layers bridged by cis Ni(H2O)4O(2) octahedra. O-(HO)-O-... hydrogen bonds help to stabilize the structure. The Ni atom and two water O atoms occupy special positions with mirror symmetry.
引用
收藏
页码：I108 / I110
页数：3
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