Preorganized Frustrated Lewis Pairs

被引：197

作者：

Bertini, Federica ^{[1
]}

Lyaskoyskyy, Volodymyr ^{[1
]}

Timmer, Brian J. J. ^{[1
]}

de Kanter, Frans J. J. ^{[1
]}

Lutz, Martin ^{[2
]}

Ehlers, Andreas W. ^{[1
]}

Slootweg, J. Chris ^{[1
]}

Lammertsma, Koop ^{[1
]}

机构：

[1] Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 01期

关键词：

FREE CATALYTIC-HYDROGENATION; HETEROLYTIC DIHYDROGEN ACTIVATION; ADDITION-REACTIONS; H-2; ACTIVATION; REACTIVITY; BORANE; MECHANISM; IMINES; CO2; PHOSPHINES;

D O I：

10.1021/ja210214r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu(2)PCH(2)BPh(2) with H-2, CO2, and isocyanates and supported computationally.

引用

页码：201 / 204

页数：4

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