Recent Advances in Phosphine-Promoted (4+1) Annulation Reactions

被引：31

作者：

Zhang, Heng ^{[1
]}

Zhou, Rong ^{[1
]}

机构：

[1] Taiyuan Univ Technol, Coll Chem & Chem Engn, Taiyuan 030024, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 2020卷 / 27期

基金：

中国国家自然科学基金;

关键词：

Phosphine; Annulation; Homogeneous catalysis; Reaction mechanisms; Heterocycles; BAYLIS-HILLMAN CARBONATES; REDUCTIVE 1+4 ANNULATION; O-QUINONE METHIDES; ALPHA-KETO ESTERS; ACCESS; MALEIMIDES; ISATINS; REARRANGEMENT; CONDENSATION; DERIVATIVES;

D O I：

10.1002/ejoc.202000023

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Over the past two decades, the nucleophilic phosphine catalysis has effected many powerful annulation reactions and emerged as an intriguing platform for the generation of highly functionalized carbo- and heterocycles. In addition to the well-established (3 + 2) annulation, the phosphine-promoted (4 + 1) annulation has received increasing attention and developed rapidly in recent years, which complements the (3 + 2) annulation and also provides an alternative approach to structurally diverse five-membered carbo- and heterocycles. This minireview summarizes the recent advances in phosphine-promoted (4 + 1) annulation reactions according to the type of substrates used in the annulations.

引用

页码：4098 / 4107

页数：10

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