One trinuclear iron(III) cluster containing a triangular Fe3(μ3-O) core: crystal structure, fluorescence and Hirshfeld surface analysis

被引：0
|
作者：
Feng, Chao [1 ]
Guo, Jing-Jing [1 ,2 ]
Wang, Kai-Lun [1 ]
机构：
[1] Bengbu Univ, Sch Mat & Chem Engn, Bengbu, Peoples R China
[2] Bengbu Univ, Sch Mech & Vehicle Engn, Bengbu, Peoples R China
来源：
INORGANIC AND NANO-METAL CHEMISTRY | 2022年
关键词：
Fe(III) cluster; crystal structure; fluorescence; Hirshfeld surface; COORDINATION POLYMERS; PI-INTERACTIONS; COMPLEXES; PHOTOLUMINESCENT; ZN(II); CU(II); ACID;
D O I：
10.1080/24701556.2022.2072343
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A triazole carboxylic complex, namely, [Fe-3(mu(3)-O)(pmta)(6)(H2O)(3)]center dot Cl (1), (Hpmta: 5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid) has been synthesized under solvothermal conditions, and the crystal structure was determined by single crystal X-ray diffraction. The X-ray study reveals that complex 1 is a trinuclear cluster containing a triangular Fe-3(mu(3)-O) core. The fluorescent property of the title complex was examined in liquid state and compared with the free ligand. In order to investigate the intermolecular interactions, we also studied the Hirshfeld surface analysis of 1. The Hirshfeld surface shows that the main intermolecular interactions are H center dot center dot center dot H and N center dot center dot center dot H/H center dot center dot center dot N interactions.
引用
收藏
页数：5
相关论文
共 50 条
  • [31] Synthesis and X-ray structure of the [{Fe3(CO)9(μ3-O)}2H]3- trianion:: dimerization of a metal carbonyl cluster via formation of an exceptionally short hydrogen bond
    Femoni, Cristina
    Iapalucci, Maria Carmela
    Longoni, Giuliano
    Zacchini, Stefano
    Zazzaroni, Enrico
    DALTON TRANSACTIONS, 2007, (25) : 2644 - 2651
  • [32] Hexanuclear iron(III) salicylaldoximato complexes presenting the [Fe6(μ3-O)2(μ2-OR)2]12+ core:: Syntheses, crystal structures, and spectroscopic and magnetic characterization
    Raptopoulou, CP
    Boudalis, AK
    Sanakis, Y
    Psycharis, V
    Clemente-Juan, JM
    Fardis, M
    Diamantopoulos, G
    Papavassillou, G
    INORGANIC CHEMISTRY, 2006, 45 (05) : 2317 - 2326
  • [33] Crystal structure, Hirshfeld surface analysis and density functional theory study of 1-nonyl-3-phenylquinoxaim-2-one
    Abad, Nadeem
    Chkirate, Karim
    Al-Ostoot, Fares Hezam
    Van Meervelt, Luc
    Lahmidi, Sanae
    Ferfra, Souad
    Ramli, Youssef
    Essassi, El Mokhtar
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 1037 - +
  • [34] Hydrothermal synthesis and crystal structure of a three-dimensional metal selenite containing double helical chains:: Fe3(H2O)(SeO3)3
    Xiao, DR
    Hou, Y
    Wang, EB
    An, HY
    Lü, H
    Li, YG
    Xu, L
    Hu, CW
    JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (08) : 2699 - 2704
  • [35] RESEARCH ON TRINUCLEAR MOLYBDENUM CLUSTER COMPOUNDS——CRYSTAL AND MOLECULAR STRUCTURE OF （Et4N）2[Mo3（μ3-O）(μ3-Cl)（μ2-Cl）3Cl6]·EtOH
    商茂虞
    黄金陵
    卢嘉锡
    Science China Chemistry, 1985, (06) : 561 - 568
  • [36] Computational study of exchange coupling in homo- and heterometallic oxo- and carboxylato bridged trinuclear complexes with triangular {Fe2IIIM(μ3-O)} (M = FeIII, NiII, CoII) core
    Shcherbakov, Igor N.
    Ivanova, Tatiana M.
    Kiskin, Mikhail A.
    Kolotilov, Sergey V.
    Novotortsev, Vladimir M.
    Eremenko, Igor L.
    Kogan, Victor A.
    INORGANICA CHIMICA ACTA, 2014, 421 : 507 - 512
  • [37] Synthesis and molecular and crystal structure of [Fe3III (μ3-O)(CH3COO)6(H2O)3]4[SiW12O40] • 19H2O
    Izarova, NV
    Sokolov, MN
    Dolgushin, FM
    Antipin, MY
    Fedin, VP
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2004, 49 (05) : 690 - 693
  • [38] Crystal structure and Hirshfeld surface analysis of 3-[2-(3,5-dimethylphenyl)hydrazinylidene]benzofuran-2(3H)-one
    Atioglu, Zeliha
    Akkurt, Mehmet
    Shikhaliyev, Namiq Q.
    Askerova, Ulviyya F.
    Mukhtarova, Sevinc H.
    Askerov, Rizvan K.
    Bhattarai, Ajaya
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 1280 - +
  • [39] SYNTHESIS, STRUCTURE AND MAGNETISM OF A TETRANUCLEAR FE(III) COMPLEX CONTAINING AN [FE4(MU(3)-O)2]8+ CORE
    CHAUDHURI, P
    WINTER, M
    FLEISCHHAUER, P
    HAASE, W
    FLORKE, U
    HAUPT, HJ
    INORGANICA CHIMICA ACTA, 1993, 212 (1-2) : 241 - 249
  • [40] Crystal Structure and Hirshfeld Surface Analysis of 3-(pyrrolidine-1-carbonyl)-2H-Chromen-2-One
    Odame, F.
    Madanhire, T.
    Hosten, E. C.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2024, 65 (07) : 1305 - 1316
12345