(1-{2-[2-(2-Ammonioethylamino)ethylamino]ethyliminomethyl}-2-naphtholato-k4O,N,N′,N") chloridocopper(II) chloride

被引：0
|
作者：
Xue, Ruiting
Niu, Meiju
机构：
[1] College of Chemistry and Chemical Engineering, Liaocheng University
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536807064033
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the square-pyramidal title complex, [CuCl(C17H24N4O)]Cl, the Cu-II atom is coordinated by three N atoms [Cu-N 1.946 (2), 2.010 (2), 2.085 (3) angstrom], one O atom [Cu-O 1.910 (2) angstrom] and one apical Cl atom [Cu-Cl 2.6437 (9) angstrom]. The three coordinated N and one O atom are almost coplanar, with a maximum deviation of 0.0268 angstrom. The tetradentate ligand forms two five-membered (N-Cu-N) and one six-membered (N-Cu-O) chelate rings with bite angles of 84.06 (10), 85.30 (10) and 91.70 (9)degrees, respectively. The two N-Cu -N chelate rings are non-planar.
引用
收藏
页码：M118 / U1161
页数：10
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