(1-{2-[2-(2-Ammonioethylamino)ethylamino]ethyliminomethyl}-2-naphtholato-k4O,N,N′,N") chloridocopper(II) chloride

被引:0
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作者
Xue, Ruiting
Niu, Meiju
机构
[1] College of Chemistry and Chemical Engineering, Liaocheng University
关键词
D O I
10.1107/S1600536807064033
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the square-pyramidal title complex, [CuCl(C17H24N4O)]Cl, the Cu-II atom is coordinated by three N atoms [Cu-N 1.946 (2), 2.010 (2), 2.085 (3) angstrom], one O atom [Cu-O 1.910 (2) angstrom] and one apical Cl atom [Cu-Cl 2.6437 (9) angstrom]. The three coordinated N and one O atom are almost coplanar, with a maximum deviation of 0.0268 angstrom. The tetradentate ligand forms two five-membered (N-Cu-N) and one six-membered (N-Cu-O) chelate rings with bite angles of 84.06 (10), 85.30 (10) and 91.70 (9)degrees, respectively. The two N-Cu -N chelate rings are non-planar.
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页码:M118 / U1161
页数:10
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