Configurational stability of propargyl zinc reagents

被引：0
|
作者：
Poisson, JF [1 ]
Chemla, F [1 ]
Normant, JF [1 ]
机构：
[1] Univ Paris 06, CNRS, Lab Chim Organoelements, F-75252 Paris 05, France
来源：
SYNLETT | 2001年 / 02期
关键词：
imines; zinc; diastereoselectivity; amino ethers; chiral resolution;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
According to the <<Hoffmann test>>, allenylzinc bromides derived from allenyllithium have been reacted with racemic and non-racemic alpha -alkoxy-imines at various temperatures. The ratio of the diastereomeric alpha -aminoethers thus obtained points to an appreciable configurational stability of the organometallics.
引用
收藏
页码：305 / 307
页数：3
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