Ionic liquids are not innocent in Pd catalysis. C-H arylation of thiazolium and imidazolium ionic liquids with aryl halides

被引：15
|
作者：
Fukuyama, Takahide [1 ]
Rahman, Md Taifur [1 ]
Mashima, Hiroshi [1 ]
Takahashi, Hideo [1 ]
Ryu, Ilhyong [1 ,2 ]
机构：
[1] Osaka Prefecture Univ, Grad Sch Sci, Dept Chem, Sakai, Osaka 5998531, Japan
[2] Natl Chiao Tung Univ, Dept Appl Chem, Hsinchu 30010, Taiwan
来源：
ORGANIC CHEMISTRY FRONTIERS | 2017年 / 4卷 / 09期
关键词：
CROSS-COUPLING REACTIONS; N-HETEROCYCLIC CARBENE; CATALYZED DIRECT ARYLATION; MIZOROKI-HECK REACTION; AMINO-ACID; MICROFLOW SYSTEM; NHC COMPLEXES; CARBONYLATION; REACTIVITY; MEDIA;
D O I：
10.1039/c7qo00331e
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The ionic liquids bearing an aromatic vinylic C-H moiety are not innocent during Pd-catalyzed crosscoupling reactions of aryl halides, since palladium-catalyzed direct C-H arylation of thiazolium and imidazolium ionic liquids competes.
引用
收藏
页码：1863 / 1866
页数：4
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