Rapid synthesis of 1-amidoalkyl-2-naphthols over sulfonic acid functionalized imidazolium salts

被引:225
|
作者
Zolfigol, Mohammad Ali [1 ]
Khazaei, Ardeshir [1 ]
Moosavi-Zare, Ahmad Reza [1 ]
Zare, Abdolkarim
Khakyzadeh, Vahid [1 ]
机构
[1] Bu Ali Sina Univ, Fac Chem, Hamadan 6517838683, Iran
关键词
Ionic liquid; Sulfonic acid functionalized imidazolium salts; beta-Naphthol; 1-Amidoalkyl-2-naphthol; Solvent-free; SOLVENT-FREE CONDITIONS; ONE-POT SYNTHESIS; CATALYST-FREE PROTOCOL; IONIC LIQUID; AMIDOALKYL NAPHTHOLS; ROOM-TEMPERATURE; EFFICIENT; CHLORIDE; ALDEHYDES; GREEN;
D O I
10.1016/j.apcata.2011.04.013
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Novel sulfonic acid functionalized imidazolium salts including 3-methyl-1-sulfonic acid imidazolium chloride {[Msim]Cl} (an ionic liquid), 1,3-disulfonic acid imidazolium chloride {[Dsim]Cl} (an ionic liquid) and 3-methyl-1-sulfonic acid imidazolium tetrachloroaluminate {[Msim]AlCl(4)} (a solid) efficiently catalyze one-pot multi-component condensation of beta-naphthol with aromatic aldehydes and amide derivatives under solvent-free conditions to afford 1-amidoalkyl-2-naphthols in excellent yields (81-96%) and in very short reaction times (1-40 min). (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:70 / 81
页数:12
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