Co-Fe/Al2O3 Nanocomposite Catalysts of the Process of CO2 Hydrogenation

被引:1
|
作者
Dyachenko, A. G. [1 ,2 ,4 ]
Ischenko, O., V [1 ]
Borysenko, M., V [2 ]
Gaidai, S., V [1 ]
Yatsymyrskyi, A., V [1 ]
Tsapyuk, G. G. [1 ]
Pryhunova, O., V [1 ]
Kostyrko, O. O. [3 ]
机构
[1] Taras Shevchenko Kyiv Natl Univ, Kiev, Ukraine
[2] NAS Ukraine, OO Chuiko Inst Surface Chem, Kiev, Ukraine
[3] OO Bogomolets Natl Med Univ, Kiev, Ukraine
[4] Polish Acad Sci, Inst Phys Chem, Warsaw, Poland
关键词
nanocomposites; bimetallic catalysts; aluminum oxide; catalytic hydrogenation of CO2; METHANATION;
D O I
10.1007/s11237-022-09731-8
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Effective catalysts of CO2 hydrogenation towards methane were obtained by impregnation of aluminum oxide with cobalt and iron nitrates. The catalysts have been characterized by XRD, SEM-EDX, argon physisorption, and TPD with mass-spectroscopy analysis. It is shown that an increase in the amount of applied Co-Fe active mass in the composition of a nanocomposite catalyst leads to an increase in the CO2 conversion and CH4 yield.
引用
收藏
页码:134 / 142
页数:9
相关论文
共 50 条
  • [41] CO2 reforming of methane over Co-Pd/Al2O3 catalysts
    Itkulova, SS
    Zhunusova, KZ
    Zakumbaeva, GD
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2005, 26 (12) : 2017 - 2020
  • [42] Effect of nanocrystalline χ-Al2O3 structure on the catalytic behavior of Co/Al2O3 in CO hydrogenation
    Chaitree, Wasu
    Jiemsirilers, Sirithan
    Mekasuwandumrong, Okorn
    Jongsomjit, Bunjerd
    Shotipruk, Artiwan
    Panpranot, Joongjai
    [J]. CATALYSIS TODAY, 2011, 164 (01) : 302 - 307
  • [43] Surface coordinate geometry of iron catalysts: Distinctive behaviors of Fe/Al2O3 in CO hydrogenation
    Kou, Y
    Wang, HL
    Niu, JZ
    Ji, WJ
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (06): : 2330 - 2333
  • [44] Correlation between the porosity of γ-Al2O3 and the performance of CuO-ZnO-Al2O3 catalysts for CO2 hydrogenation into methanol
    Nguyen Le-Phuc
    Tri Van Tran
    Phuong Ngo Thuy
    Luong Huu Nguyen
    Thuat Thanh Trinh
    [J]. REACTION KINETICS MECHANISMS AND CATALYSIS, 2018, 124 (01) : 171 - 185
  • [45] HYDROGENATION OF CO2 ON FE/CARBON CATALYSTS
    GUERRERORUIZ, A
    LOPEZGONZALEZ, JD
    RODRIGUEZRAMOS, I
    RODRIGUEZREINOSO, F
    [J]. REACTION KINETICS AND CATALYSIS LETTERS, 1986, 31 (02): : 349 - 354
  • [46] Probing the Reactive Intermediates in CO2 Hydrogenation on Ni/Al2O3 Catalysts with Modulation Excitation Spectroscopy
    Kock, Mikkel
    Kowalewski, Emil
    Iltsiou, Dimitra
    Mielby, Jerrik
    Kegnaes, Soren
    [J]. CHEMCATCHEM, 2024, 16 (04)
  • [47] Hydrogenation of CO2 to formic acid catalyzed by heterogeneous Ru-PPh3/Al2O3 catalysts
    Zhang, Wenjing
    Wang, Shengping
    Zhao, Yujun
    Ma, Xinbin
    [J]. FUEL PROCESSING TECHNOLOGY, 2018, 178 : 98 - 103
  • [48] Methanol synthesis by CO2 hydrogenation over titanium modified γ-Al2O3 supported copper catalysts
    Qi, GX
    Fei, JH
    Hou, ZY
    Zheng, XM
    [J]. REACTION KINETICS AND CATALYSIS LETTERS, 2001, 73 (01): : 151 - 160
  • [49] Methanol Synthesis by co2 Hydrogenation over Titanium Modified γ -al2o3 Supported Copper Catalysts
    Gong-Xin Qi
    Jin-Hua Fei
    Zhao-Yin Hou
    Xiao-Ming Zheng
    [J]. Reaction Kinetics and Catalysis Letters, 2001, 73 : 151 - 160
  • [50] Methanol Synthesis by CO2 Hydrogenation overCu/ZnO/Al2O3 Catalysts under Fluctuating Conditions
    Zurbel, Alexander
    Kraft, Michael
    Kavurucu-Schubert, Sena
    Bertau, Martin
    [J]. CHEMIE INGENIEUR TECHNIK, 2018, 90 (05) : 721 - 724