Bis(pentane-2,4-dionato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cobalt(II)

被引：4
|
作者：
Perdih, Franc [1 ,2 ]
机构：
[1] Univ Ljubljana, Fac Chem & Chem Technol, SI-1000 Ljubljana, Slovenia
[2] CO EN FIST, SI-1000 Ljubljana, Slovenia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
data-to-parameter ratio = 17.1; mean σ(C-C) = 0.002 Å; R factor = 0.032; single-crystal X-ray study; T = 293 K; wR factor = 0.089;
D O I：
10.1107/S1600536811046216
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Co(C5H7O2)(2)(C12H8N2)], the Co-II cation lies on a twofold rotation axis and is coordinated by four O atoms from two acetylacetonate (acac) ligands and two N atoms from a 1,10-phenanthroline (phen) ligand in a slightly distorted octahedral environment, with Co-O bond lengths of 2.0565 (11) and 2.0641 (11) angstrom and Co-N bond lengths of 2.1630 (12) angstrom. In the crystal, there are no significant hydrogen-bonding or pi-pi interactions.
引用
收藏
页码：M1697 / U145
页数：8
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