One-pot synthesis of α-diazo-β-hydroxyesters under phase-transfer catalysis and application to the catalytic asymmetric aldol reaction

被引：36
|
作者：
Arai, S [1 ]
Hasegawa, K [1 ]
Nishida, A [1 ]
机构：
[1] Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 05期
关键词：
Aldol reaction; ammonium salt; asymmetric synthesis; diazoester; phase transfer;
D O I：
10.1016/j.tetlet.2003.11.083
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The one-pot (three steps) synthesis of alpha-diazo-beta-hydroxyesters from tosyl chloride under phase-transfer catalysis is described. The catalytic asymmetric aldol reaction between a diazoester and aldehydes was also investigated and gave moderate to good enantioselectivity. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1023 / 1026
页数：4
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