High resolution photo-absorption studies of acrylonitrile, C2H3CN, and acetonitrile, CH3CN

被引:30
|
作者
Eden, S
Limao-Vieira, P
Kendall, P
Mason, NJ
Hoffmann, SV
Spyrou, SM
机构
[1] UCL, Dept Phys & Astron, London WC1E 6BT, England
[2] Aarhus Univ, Inst Storage Rings, DK-8000 Aarhus C, Denmark
[3] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece
[4] Univ Nova Lisboa, FCT, Dept Fis, P-2829516 Caparica, Portugal
[5] IST, Ctr Fis Mol, P-1049001 Lisbon, Portugal
[6] Open Univ, Dept Phys & Astron, Ctr Mol & Opt Sci, Milton Keynes MK7 6AA, Bucks, England
来源
EUROPEAN PHYSICAL JOURNAL D | 2003年 / 26卷 / 02期
关键词
D O I
10.1140/epjd/e2003-00223-5
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
High resolution photo-absorption spectra of acrylonitrile and acetonitrile have been recorded in the wavelength range 115 to 320 nm (10.8 to 3.9 eV). Results are compared with previous photo-absorption measurements and electron energy loss spectra and, in most cases, are found to be in close agreement. The high resolution achieved in the present work has allowed some structures to be observed for the first time and new assignments have been suggested accordingly. The role of the molecules in the terrestrial atmosphere is discussed.
引用
收藏
页码:201 / 210
页数:10
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