Iron(III)-catalyzed radical α,β-aminophosphinoylation of styrenes with diphenylphosphine oxides and anilines

被引：14
|
作者：
Wang, Yu [1 ]
Wang, Wei [1 ]
Tang, Ruyun [1 ]
Liu, Zhenhua [2 ]
Tao, Weihua [1 ]
Fang, Zhongxue [1 ]
机构：
[1] Yancheng Teachers Univ, Sch Chem & Environm Engn, Yancheng 224007, Peoples R China
[2] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Shandong, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2018年 / 16卷 / 42期
关键词：
PHOSPHORUS-CENTERED RADICALS; BETA-KETOPHOSPHONATES; BIOLOGICAL EVALUATION; UNACTIVATED ALKENES; REDUCTIVE AMINATION; H FUNCTIONALIZATION; CASCADE CYCLIZATION; BOND FORMATION; AMP MIMICS; PHOSPHONATES;
D O I：
10.1039/c8ob02151a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A Fe-catalyzed highly regioselective ,-difunctionalization of vinylarenes with diphenylphosphine oxides and anilines is disclosed, in which ,-aminophosphinoylation is efficiently and conveniently constructed under mild conditions with good functional compatibility and a broad substrate scope. The control experiments have revealed a radical reaction pathway.
引用
收藏
页码：7782 / 7786
页数：5
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