Activation of diatomic molecules at solid surface

被引：6

作者：

Ertl, G ^{[1
]}

机构：

[1] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany

来源：

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2005年 / 363卷 / 1829期

关键词：

single crystal surfaces; adsorption; heterogeneous catalysis;

D O I：

10.1098/rsta.2004.1530

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The interaction of a diatomic molecule with a well-defined single crystal surface represents the prototype of the elementary processes involved in heterogeneous catalysis, and it can be studied down to atomic length and extremely short (fs) time-scales. Our present understanding is illustrated by examples concerning the activation of hydrogen (including also the breakdown of thermal equilibrium during rapid laser-induced associative desorption), the role of steps as 'active sites' in the dissociative adsorption of NO or N-2, and the mechanism and kinetics of the catalytic oxidation of CO.

引用

页码：955 / 958

页数：4

共 50 条

[41] Modeling Spectra of Diatomic Molecules
Havalyova, I.
Pashov, A.
[J]. 10TH JUBILEE CONFERENCE OF THE BALKAN PHYSICAL UNION, 2019, 2075
[42] THE HYPERFINE SPECTRA OF DIATOMIC MOLECULES
FROSCH, RA
FOLEY, HM
[J]. PHYSICAL REVIEW, 1951, 82 (02): : 337 - 338
[43] Dissociation energy of diatomic molecules
Sarvpreet Kaur
C G Mahajan
[J]. Pramana, 1998, 50 : 397 - 403
[44] The chiral effect of adsorption of univalent atoms and diatomic molecules on the surface of carbon nanotubes
Shamina, E. N.
Lebedev, N. G.
[J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B, 2012, 6 (03) : 448 - 454
[45] VIBRATIONAL RELAXATION OF DIATOMIC MOLECULES
KUKSENKO, BV
LOSEV, SA
[J]. HIGH TEMPERATURE, 1968, 6 (05) : 759 - &
[46] VIBRATIONAL RELAXATION OF DIATOMIC MOLECULES
NIKITIN, EE
[J]. DOKLADY AKADEMII NAUK SSSR, 1959, 124 (05): : 1085 - 1088
[47] Dissociation energies of diatomic molecules
Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China
[J]. Chin. Phys. Lett, 2008, 6 (2012-2015):
[48] Dissociation energies of diatomic molecules
Fan Qun-Chao
Sun Wei-Guo
[J]. CHINESE PHYSICS LETTERS, 2008, 25 (06) : 2012 - 2015
[49] Potential function for diatomic molecules
Birajdar, SV
Kadam, CJ
Shelke, RM
Behere, SH
[J]. INDIAN JOURNAL OF PURE & APPLIED PHYSICS, 2005, 43 (06) : 427 - 431
[50] DIPOLE MOMENTS OF DIATOMIC MOLECULES
GRAY, BF
PRITCHARD, HO
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1958, 2 (02) : 137 - 143

← 1 2 3 4 5 →