Activation of diatomic molecules at solid surface

被引：6

作者：

Ertl, G ^{[1
]}

机构：

[1] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany

来源：

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2005年 / 363卷 / 1829期

关键词：

single crystal surfaces; adsorption; heterogeneous catalysis;

D O I：

10.1098/rsta.2004.1530

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The interaction of a diatomic molecule with a well-defined single crystal surface represents the prototype of the elementary processes involved in heterogeneous catalysis, and it can be studied down to atomic length and extremely short (fs) time-scales. Our present understanding is illustrated by examples concerning the activation of hydrogen (including also the breakdown of thermal equilibrium during rapid laser-induced associative desorption), the role of steps as 'active sites' in the dissociative adsorption of NO or N-2, and the mechanism and kinetics of the catalytic oxidation of CO.

引用

页码：955 / 958

页数：4

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[2] Study of surface in the energy transfer of diatomic molecules to solid surfaces
Zolotoukhina, TN
[J]. MICROSCALE THERMOPHYSICAL ENGINEERING, 1997, 1 (02): : 127 - 135
[3] ON NONELASTIC REFLECTION OF DIATOMIC-MOLECULES FROM A SOLID-SURFACE
GERASIMENKO, VI
[J]. UKRAINSKII FIZICHESKII ZHURNAL, 1980, 25 (11): : 1818 - 1823
[4] SIMPLE CLASSICAL MODEL FOR SCATTERING OF DIATOMIC-MOLECULES FROM A SOLID SURFACE
DOLL, JD
[J]. JOURNAL OF CHEMICAL PHYSICS, 1973, 59 (03): : 1038 - 1042
[5] VIBRATION FREQUENCIES IN DIATOMIC MOLECULES AND IN SOLID METALS
BAUGHAN, EC
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1952, 48 (02): : 121 - 128
[6] POTENTIAL SURFACE CROSSINGS FOR DIATOMIC-MOLECULES
BERRONDO, M
ROJAS, DH
[J]. INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 1975, 9 (01) : 119 - 131
[7] COLLISION OF A DIATOMIC MOLECULE WITH A SOLID SURFACE
WOLKEN, G
[J]. JOURNAL OF CHEMICAL PHYSICS, 1973, 59 (03): : 1159 - 1165
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PARILIS, ES
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