Intramolecular Cross-linking of Polymers Using Difunctional Acetylenes via Click Chemistry

被引：22

作者：

Cengiz, Halime ^{[1
]}

Aydogan, Binnur ^{[1
]}

Ates, Sahin ^{[1
,2
]}

Acikalin, Engin ^{[1
,2
]}

Yagci, Yusuf ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

[2] TUBITAK Marmara Res Ctr, TR-41470 Gebze, Kocaeli, Turkey

来源：

DESIGNED MONOMERS AND POLYMERS | 2011年 / 14卷 / 01期

关键词：

Intramolecular cross-linking; free radical polymerization; click chemistry; poly(styrene-co-chloromethyl styrene); TRANSFER RADICAL POLYMERIZATION; DENDRONIZED LINEAR-POLYMERS; ONE-POT SYNTHESIS; DIELS-ALDER; 1,3-DIPOLAR CYCLOADDITIONS; POLYSTYRENE NANOPARTICLES; TRIBLOCK COPOLYMERS; MATERIALS SCIENCE; TERMINAL ALKYNES; EFFICIENT ROUTE;

D O I：

10.1163/138577210X541213

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An efficient approach was described for the intramolecular cross-linking of azide-functionalized poly(styrene-co-chloromethyl styrene) co-polymers (PS-N-3) via click chemistry at room temperature. Reaction of PS-N-3 with the appropriate diacetylene functional compounds such as 1,4-diethynylbenzene (DEB) and 1,10-dipropargyloxy decane (DPD) in ultra-dilute solutions led to unimolecular particle-like structures. The resulting polymers were characterized in detail by H-1-NMR, FT-IR, GPC and DSC measurements. (C) Koninklijke Brill NV, Leiden, 2011

引用

页码：69 / 78

页数：10

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