Synthesis and structure of a Mo3S4 cluster complex with seven cluster electrons

被引：28
|
作者：
Cramer, RE [1 ]
Yamada, K [1 ]
Kawaguchi, H [1 ]
Tatsumi, K [1 ]
机构：
[1] UNIV HAWAII,DEPT CHEM,HONOLULU,HI 96822
来源：
INORGANIC CHEMISTRY | 1996年 / 35卷 / 06期
关键词：
D O I：
10.1021/ic951103z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A trinuclear molybdenum cluster having 7 d-electrons, (Cp*Mo)(3)S-4 (1), has been synthesized from reduction of Cp*Mo(S(t)Bu)(3) by Na/Hg. Extended Huckel calculations on (CpMo)(3)S-4 indicate that the unpaired electron resides in the 2e orbital, which is slightly antibonding with respect to the cluster atoms. In fact, the Mo3S43+ cluster expands compared with a 6 electron Mo3S44+ core. We found evidence for a distortion of the cluster, albeit very small, due to the Jahn-Teller effect.
引用
收藏
页码：1743 / &
页数：5
相关论文
共 50 条
  • [41] Synthesis, structure and NMR studies of trinuclear Mo3S4 clusters coordinated with dithiophosphate and chiral carboxylate ligands
    Gushchin, Artem L.
    Hernandez-Molina, Rita
    Anyushin, Alexander V.
    Gallyamov, Marsel R.
    Gonzalez-Platas, Javier
    Moroz, Nikolay K.
    Sokolov, Maxim N.
    NEW JOURNAL OF CHEMISTRY, 2016, 40 (09) : 7612 - 7619
  • [42] Synthesis and Crystal Structure of an Incomplete Cubane-type Mo3S4 Cluster with the N-N-O Type Tridentate Ligand: {Mo3S4[NH2CH2CH（O）CH2NH2]3}（DTP）·（H2O）2·（DMF）
    HU Rui-Feng QIN Ye-Yan KANG Yao ZHANG Jian WEN Yi-Hang LI Zhao-Ji CHEN Jiu-Tong YAO Yuan-Gen (State Key Laboratory of Structural Chemistry
    Chinese Journal of Structural Chemistry, 2005, (07) : 751 - 754
  • [43] SUBSTITUTION OF SULFUR IN THE MO6CL84+ CLUSTER - SYNTHESIS AND STRUCTURE OF 2 COMPOUNDS WITH THE MO6CL7S3+ CLUSTER UNIT
    MICHEL, JB
    MCCARLEY, RE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 179 (MAR): : 133 - INOR
  • [44] THE SYNTHESIS AND CRYSTAL STRUCTURE OF A NOVEL MOLYBDENUM-SULFUR CLUSTER COMPLEX, （NH4）4[Mo3（NO）4S13]·3H2O
    汤卡罗
    金祥林
    唐有祺
    Science China Chemistry, 1984, (07) : 657 - 664
  • [45] Cuboidal oxalate cluster complexes with the Mo3CuQ45+ cluster core (Q = S or Se):: synthesis, structure, and electrochemical properties
    Gushchin, A. L.
    Kovalenko, K. A.
    Sokolov, M. N.
    Naumov, D. Yu.
    Zakharchuk, N. F.
    Vicent, C.
    Fedin, V. P.
    RUSSIAN CHEMICAL BULLETIN, 2007, 56 (09) : 1701 - 1706
  • [46] Cuboidal oxalate cluster complexes with the Mo3CuQ45+ cluster core (Q = S or Se): synthesis, structure, and electrochemical properties
    A. L. Gushchin
    K. A. Kovalenko
    M. N. Sokolov
    D. Yu. Naumov
    N. F. Zakharchuk
    C. Vicent
    V. P. Fedin
    Russian Chemical Bulletin, 2007, 56 : 1701 - 1706
  • [47] Synthesis and Characterization of [Mo3S4(NDABu)(HNDABu)2]3- and [Mo3S4(HNDAPr)3]2- Anions as Building Blocks for Organic-Inorganic Hybrid Solids
    Duval, Sylvain
    Dumur, Frederic
    Guenee, Laure
    Marrot, Jerome
    Simonnet-Jegat, Corine
    Cadot, Emmanuel
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, (07) : 1149 - 1156
  • [48] Structure and functional dynamics of the mitochondrial Fe/S cluster synthesis complex
    Boniecki, Michal T.
    Freibert, Sven A.
    Muehlenhoff, Ulrich
    Lill, Roland
    Cygler, Miroslaw
    NATURE COMMUNICATIONS, 2017, 8
  • [49] Structure and functional dynamics of the mitochondrial Fe/S cluster synthesis complex
    Michal T. Boniecki
    Sven A. Freibert
    Ulrich Mühlenhoff
    Roland Lill
    Miroslaw Cygler
    Nature Communications, 8
  • [50] SYNTHESIS, STRUCTURE, AND MOLECULAR-ORBITAL CALCULATION OF THE BICAPPED TRIANGULAR MOLYBDENUM CLUSTER COMPLEX [MO3S5(PME(3))(6)]
    TSUGE, K
    IMOTO, H
    SAITO, T
    INORGANIC CHEMISTRY, 1995, 34 (13) : 3404 - 3409
12345