Cobalt(II)-catalyzed oxidation of alcohols into carboxylic acids and ketones with hydrogen peroxide

被引：86
|
作者：
Das, S [1 ]
Punniyamurthy, T [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Gauhati 781039, India
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 32期
关键词：
oxidation; alcohols; catalyst; hydrogen peroxide; cobalt(II) complex;
D O I：
10.1016/S0040-4039(03)01479-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The oxidation of aliphatic and aromatic alcohols into the corresponding carboxylic acid analogues and ketones has been carried out using 30% H2O2 and cobalt(II) complex 1 in good to high yields. The reaction is safe, clean and functions in the absence of additives. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6033 / 6035
页数：3
相关论文
共 50 条
  • [41] OXIDATION OF STEROIDAL KETONES .V. SELENIUM DIOXIDE CATALYZED HYDROGEN PEROXIDE OXIDATION OF STEROIDAL CONJUGATED KETONES
    CASPI, E
    SHIMIZU, Y
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1965, 30 (01): : 223 - &
  • [42] Organophotocatalytic oxidation of alcohols to carboxylic acids
    Tambe, Shrikant D.
    Cho, Eun Jin
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2022, 43 (11) : 1226 - 1230
  • [43] Carboxylic acids from primary alcohols and aldehydes by a pyridinium chlorochromate catalyzed oxidation
    Hunsen, M
    [J]. SYNTHESIS-STUTTGART, 2005, (15): : 2487 - 2490
  • [44] Studies on Iron-Catalyzed Aerobic Oxidation of Benzylic Alcohols to Carboxylic Acids
    Jiang, Xingguo
    Ma, Shengming
    [J]. SYNTHESIS-STUTTGART, 2018, 50 (08): : 1629 - 1639
  • [45] Oxidation of primary alcohols to carboxylic acids with sodium chlorite catalyzed by TEMPO and bleach
    Zhao, MZ
    Li, J
    Mano, E
    Song, ZG
    Tschaen, DM
    Grabowski, EJJ
    Reider, PJ
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (07): : 2564 - 2566
  • [46] Effect of Quinones on the Cobalt(II) Acetate–Catalyzed Mild Oxidation of Cyclohexane with Hydrogen Peroxide in Acetic Acid
    A. P. Pokutsa
    A. B. Zaborovskii
    R. B. Sheparovich
    V. I. Kopylets
    D. S. Maksim-Lutsik
    [J]. Kinetics and Catalysis, 2003, 44 : 121 - 128
  • [47] Methyltrioxorhenium catalyzed oxidative cleavage of α-hydroxycarbonyl compounds to carboxylic acids with hydrogen peroxide
    Jain, SL
    Sharma, VB
    Sain, B
    [J]. SYNTHETIC COMMUNICATIONS, 2003, 33 (22) : 3875 - 3878
  • [48] Cobalt phthalocyanine catalyzed aerobic oxidation of secondary alcohols: an efficient and simple synthesis of ketones
    Sharma, VB
    Jain, SL
    Sain, B
    [J]. TETRAHEDRON LETTERS, 2003, 44 (02) : 383 - 386
  • [49] Regioselective hydroxylactonization of unsaturated carboxylic acids with hydrogen peroxide catalyzed by methyltrioxorhenium.
    Tan, HS
    Espenson, JH
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U1001 - U1002
  • [50] OXIDATION OF RUTHENIUM COORDINATED ALCOHOLS BY MOLECULAR-OXYGEN TO KETONES AND HYDROGEN-PEROXIDE
    TOVROG, BS
    DIAMOND, SE
    MARES, F
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (17) : 5067 - 5069
12345