Synthesis, X-ray structural characterization and solution studies of a mononuclear Ni(II)-Schiff base complex bearing free formyl groups

被引：0
|
作者：
Gupta, S [1 ]
Panja, A
Shaikh, N
Goswami, S
Banerjee, P
Butcher, RJ
机构：
[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, W Bengal, India
[2] Howard Univ, Dept Chem, Washington, DC 20059 USA
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2004年 / 43卷 / 01期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new mononuclear Ni(II)-Schiff base complex has been synthesized and structurally characterized through X-ray crystallography. The compound crystallizes in the monoclinic space group C2/c (No. 15) with a = 17.268(7), b = 14.619(6) and c = 10.683(4) Angstrom. The molecular structure shows that the Ni(II) ion is in the distorted octahedral environment in which two phenolic oxygen atoms occupy the axial positions. Two -CHO groups arising out of the 2,6-diformyl-4-methylphenol remain as pendants. UV/vis and cyclic voltammetric experiments have been performed of the Ni(II) complex in DMF solution and the results compare well with the previously reported systems.
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页码：63 / 66
页数：4
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