RHODIUM COMPLEXES IMMOBILIZED ON NANOPOROUS SILICA FOR OCTENE HYDROFORMYLATION

被引：0

作者：

Yun, So-Young ^{[1
]}

Seong, Min Jun ^{[1
]}

Yim, Jin-Heong ^{[2
]}

Ko, Young Soo ^{[1
]}

Park, Young-Kwon ^{[3
]}

Jeon, Jong-Ki ^{[1
]}

机构：

[1] Kongju Natl Univ, Dept Chem Engn, Cheonan 331717, South Korea

[2] Kongju Natl Univ, Div Adv Mat Engn, Cheonan 331717, South Korea

[3] Univ Seoul, Sch Environm Engn, Seoul 130743, South Korea

来源：

REVIEWS ON ADVANCED MATERIALS SCIENCE | 2011年 / 28卷 / 02期

关键词：

CATALYSTS; ETHYLENE;

D O I：

暂无

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Rhodium was immobilized on the aminated SBA-15 in order to evaluate it as a heterogeneous catalyst for 1-octene hydroformylation. The triphenylphosphine ligand remarkably improved the activity. Hydroformylation activity of 1-octene was higher than that of branched and/or inner octenes. At a reaction temperature of 120 degrees C, hydroformylation of 1-octene was more prevailing than isomerization, and thus the nonyl aldehyde yield reached a maximum.

引用

页码：154 / 157

页数：4

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