Photo- and electroluminescence in a series of PPV type terpolymers containing fluorene, thiophene and phenylene units

被引:9
|
作者
Nowacki, Bruno [1 ]
Grova, Isabel R. [1 ]
Domingues, Raquel A. [2 ]
Faria, Gregorio C. [3 ]
Atvars, Teresa D. Z. [2 ]
Akcelrud, Leni [1 ]
机构
[1] Univ Fed Parana, Paulo Scarpa Polymer Lab LaPPS, BR-81531990 Curitiba, Parana, Brazil
[2] State Univ Campinas Unicamp, Inst Chem, BR-13084971 Campinas, SP, Brazil
[3] Univ Sao Paulo, Phys Inst Sao Carlos IFSC, BR-13560970 Sao Carlos, SP, Brazil
关键词
Fluorene; Phenylene; Thiophene; Conjugated copolymers; Photoluminescence; Electroluminescence; LIGHT-EMITTING-DIODES; ENERGY-TRANSFER; EMISSION PROPERTIES; CONJUGATED POLYMER; DE-AGGREGATION; COPOLYMER; DYNAMICS; LUMINESCENCE; DONOR; FILMS;
D O I
10.1016/j.jphotochem.2012.03.022
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The emissive properties of terpolymers with fluorene, thiophene and phenylene groups, forming alternating PPV type structures, are discussed in terms of their composition, photo- and electroluminescence properties. The fluorene groups were inserted in each phenylene-vinylene and thiophene-vinylene units, and their concentration did not vary, representing 50% of the molar composition. The ratio of thiophene-vinylene/phenylene-vinylene varied in the range 25,50 and 75%. Photo- and electroluminescence properties were strongly dependent on the thiophene-vinylene content and were compared with the fluorene-vinylene-thiophene and fluorene-vinylene-phenylene parent copolymers. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:71 / 79
页数:9
相关论文
共 50 条
  • [21] Synthesis, characterization, and electroluminescence of PPV copolymers containing electron and hole-transporting units
    Xun, Shidi
    Zhou, Quanguo
    Li, Hongchao
    Ma, Dongge
    Wang, Lixiang
    Jing, Xiabin
    Wang, Fosong
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (05) : 1566 - 1576
  • [22] New ladder-type poly(p-phenylene)s containing fluorene unit exhibiting high efficient electroluminescence
    Qiu, S
    Lu, P
    Liu, X
    Shen, FZ
    Liu, LL
    Ma, YG
    Shen, JC
    MACROMOLECULES, 2003, 36 (26) : 9823 - 9829
  • [23] Electroluminescence enhancement by blending PVK with an alternating copolymer containing triphenylamine and phenylene units
    Qiu, Y
    Duan, L
    Hu, XM
    Zhang, DQ
    Zheng, M
    Bai, FL
    SYNTHETIC METALS, 2001, 123 (01) : 39 - 42
  • [24] Photophysical Behavior of Block Copolymers Containing EDOT, Thiophene, and Benzodiathiazole Units Linked to Fluorene
    Zanlorenzi, Cristiano
    Cassemiro, Sandra M.
    Grova, Isabel R.
    Akcelrud, Leni
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2016, 54 (09) : 908 - 915
  • [25] Synthesis and electroluminescence of poly(aryleneethynylene)s based on fluorene containing hole-transport units
    Zhan, XW
    Liu, YQ
    Yu, G
    Wu, X
    Zhu, DB
    Sun, RG
    Wang, DK
    Epstein, AJ
    JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (06) : 1606 - 1611
  • [26] Photo- and electroluminescence in strong electric fields in Sb-containing narrow gap semiconductor materials
    Vinnichenko, M. Ya
    Makhov, I. S.
    Panevin, V. Yu
    Selivanov, A. V.
    Firsov, D. A.
    Vorobjev, L. E.
    Pikhtin, N. A.
    Bakhvalov, K. V.
    Shterengas, L.
    Belenky, G.
    Kipshidze, G.
    3RD INTERNATIONAL SCHOOL AND CONFERENCE ON OPTOELECTRONICS, PHOTONICS, ENGINEERING AND NANOSTRUCTURES (SAINT PETERSBURG OPEN 2016), 2016, 741
  • [27] Blue photo- and electroluminescence based on poly(2-benzoyl-1,4-phenylene) and poly(2,5-dibenzoyl-1,4-phenylene)
    Fu, H
    Yun, H
    Kwei, TK
    Okamoto, Y
    Blumstengel, S
    Walser, A
    Dorsinville, R
    POLYMERS FOR ADVANCED TECHNOLOGIES, 1999, 10 (05) : 259 - 264
  • [28] A hyperbranched copolymer of poly(dialkoxy-p-phenylenevinylene) and trivinylenephenylene units:: Synthesis, characterization, photo- and electroluminescence properties
    Wang, Hualin
    Sun, Yueming
    Qi, Zhengjian
    Kong, Fan
    Ha, Yongquan
    Yin, Shougen
    Lin, Shen
    MACROMOLECULES, 2008, 41 (10) : 3537 - 3542
  • [29] Photo- and electroluminescent properties of π-conjugated copolymer containing 2,2'-bipyridyl units
    Deichmann, Vitor Angelo Fonseca
    Cirpan, Ali
    Karasz, Frank E.
    Akcelrud, Leni
    POLYMER INTERNATIONAL, 2007, 56 (02) : 252 - 257
  • [30] Synthesis and electroluminescence properties of novel silicon-based copolymers containing oxadiazole and fluorene units for PLED
    Paik, KL
    Baek, NS
    Kim, HK
    Lee, JH
    Lee, Y
    OPTICAL MATERIALS, 2003, 21 (1-3) : 135 - 142