The emissive properties of terpolymers with fluorene, thiophene and phenylene groups, forming alternating PPV type structures, are discussed in terms of their composition, photo- and electroluminescence properties. The fluorene groups were inserted in each phenylene-vinylene and thiophene-vinylene units, and their concentration did not vary, representing 50% of the molar composition. The ratio of thiophene-vinylene/phenylene-vinylene varied in the range 25,50 and 75%. Photo- and electroluminescence properties were strongly dependent on the thiophene-vinylene content and were compared with the fluorene-vinylene-thiophene and fluorene-vinylene-phenylene parent copolymers. (C) 2012 Elsevier B.V. All rights reserved.
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Iowa State Univ, Dept Chem, Ames, IA 50011 USAIowa State Univ, Dept Chem, Ames, IA 50011 USA
Mike, Jared F.
Intemann, Jeremy J.
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Iowa State Univ, Dept Chem, Ames, IA 50011 USAIowa State Univ, Dept Chem, Ames, IA 50011 USA
Intemann, Jeremy J.
Cai, Min
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Iowa State Univ, Ames Lab USDOE, Ames, IA 50011 USA
Iowa State Univ, Dept Phys, Ames, IA 50011 USAIowa State Univ, Dept Chem, Ames, IA 50011 USA
Cai, Min
Xiao, Teng
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Iowa State Univ, Ames Lab USDOE, Ames, IA 50011 USA
Iowa State Univ, Dept Phys, Ames, IA 50011 USAIowa State Univ, Dept Chem, Ames, IA 50011 USA
Xiao, Teng
Shinar, Ruth
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Iowa State Univ, Microelect Res Ctr, Ames, IA 50011 USA
Iowa State Univ, Dept Elect Engn, Ames, IA 50011 USAIowa State Univ, Dept Chem, Ames, IA 50011 USA
Shinar, Ruth
Shinar, Joseph
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Iowa State Univ, Ames Lab USDOE, Ames, IA 50011 USA
Iowa State Univ, Dept Phys, Ames, IA 50011 USAIowa State Univ, Dept Chem, Ames, IA 50011 USA
Shinar, Joseph
Jeffries-EL, Malika
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Iowa State Univ, Dept Chem, Ames, IA 50011 USAIowa State Univ, Dept Chem, Ames, IA 50011 USA