Recent advances in multi-temperature-responsive polymeric materials

被引：79
|
作者：
Kotsuchibashi, Yohei [1 ]
机构：
[1] Shizuoka Inst Sci & Technol, Dept Mat & Life Sci, 2200-2 Toyosawa, Fukuroi, Shizuoka 4378555, Japan
来源：
POLYMER JOURNAL | 2020年 / 52卷 / 07期
关键词：
BLOCK-COPOLYMERS; UNIMOLECULAR MICELLES; N-ALKYLACRYLAMIDES; DUAL-TEMPERATURE; FACILE SYNTHESIS; CLICK CHEMISTRY; CORE; MICELLIZATION; DELIVERY; UCST;
D O I：
10.1038/s41428-020-0330-0
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Temperature-responsive (or thermoresponsive) polymers belong to the most studied class of smart polymers and are mainly classified into two types based on their temperature-responsive behavior: lower critical solution temperature (LCST) and upper critical solution temperature (UCST). Based on polymeric design, when two temperature-responsive segments are connected through a covalent bond at each chain end, the block copolymers are expected to show a dual-temperature-responsive property upon conformational changes. Moreover, in recent years, multi-temperature-responsive properties that can represent complex states/structures have been reported. These multi-temperature-responsive block copolymers can set the stage for development in various research fields, such as drug-delivery carriers, sensors in solvents, model proteins, and memory storage. This review focuses on current multi-temperature-responsive polymeric materials and their applications and is divided into three parts: (1) dual-temperature-responsive block copolymers, (2) dual-temperature-responsive hydrogels, and (3) multi-temperature-responsive block copolymers.
引用
收藏
页码：681 / 689
页数：9
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