Electrosurface properties of tungsten(VI) oxide in electrolyte solutions

被引:4
|
作者
Petrov, Yu. Yu. [1 ]
Avvakumova, S. Yu. [1 ]
Sidorova, M. P. [1 ]
Ermakova, L. E. [1 ]
Merkushev, O. M. [1 ]
机构
[1] St Petersburg State Univ, Dept Chem, St Petersburg 198504, Russia
基金
俄罗斯基础研究基金会;
关键词
SURFACE;
D O I
10.1134/S1061933X10050121
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Electrosurface characteristics of tungsten oxide in solutions of 1: 1 electrolytes are studied in a wide range of concentration and pH values. The dependence of the position of isoelectric point on the concentration of background electrolyte and the cation nature is revealed. The equilibrium constants of surface reactions, adsorption potentials of ions, specific surface conductivities, and degrees of dissociation of surface groups in the point of zero charge are calculated.
引用
收藏
页码:663 / 668
页数:6
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