Guanine binding to dirhodium tetracarboxylate anticancer complexes: quantum chemical calculations unravel an elusive mechanism

被引：0
|
作者：
Deubel, Dirk V.
Chifotides, Helen T.
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
[2] ETH, D CHAB, Zurich, Switzerland
来源：
CHEMICAL COMMUNICATIONS | 2007年 / 33期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction mechanism leading to metalated DNA fragments in which guanine-N7,O6 spans the metal-metal bond of dirhodium antitumour complexes in a bridging fashion at equatorial sites has been unravelled by a comprehensive prediction of intermediates and transition states.
引用
收藏
页码：3438 / 3440
页数：3
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