Synthesis and Spectroscopic Characterization of Some Copper(II) Trinuclear Complexes involving Nitrogen as Bridging Atoms

被引：0
|
作者：
Annapoorani, S. [1 ]
机构：
[1] PSG Coll Technol, Dept Chem, Coimbatore 641004, Tamil Nadu, India
来源：
ASIAN JOURNAL OF CHEMISTRY | 2012年 / 24卷 / 08期
关键词：
Schiff base; Trinuclear complexes; 2-Aminobenzaldehyde; Cu(II) complexes; TRIDENTATE SCHIFF-BASES; MACROCYCLIC COMPLEXES; SPECTRAL PROPERTIES; ELECTRONIC SPECTRA; ION COMPLEXES; DERIVATIVES; LIGAND; SALICYLALDEHYDE; COBALT(III); NICKEL(II);
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The following Schiff bases were employed as ligands in synthesizing Cu(II) trinuclear complexes: 1,2-bis-(2-aminobenzylideneamino) ethane (L-1), 1,2-bis-(2-aminobenzylideneamino)propane (L-2), 1,3-bis-(2-aminobenzylideneamino)propane (L-3), 1,2-bis-(2-aminobenzylideneamino)benzene (L-4). The ligands were obtained by reacting 2-aminobenzaldehyde with 1,2-diaminoethane, 1,2-diaminopropane, 1,3-diaminopropane and 1,2-diaminobenzene, respectively. Four trinuclear coordination complexes were synthesized and structurally characterized by elemental analysis, molar conductivity, FT-IR, UV-Visible, magnetic and EPR spectral studies. The results suggest that the complexes are trinuclear and ionic in nature.
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页码：3347 / 3351
页数：5
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