Synthesis and chemistry of the 16-electron osmium complex [OsBr(η5-C5Me5)(PiPr3)]

被引：0

作者：

Glaser, PB ^{[1
]}

Tilley, TD ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2001年 / 11期

关键词：

osmium; cyclopentadienyl ligands; oxidative addition; coordinative unsaturation;

D O I：

10.1002/1099-0682(200111)2001:113.0.CO;2-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The isolable 16-electron half-sandwich Cls complex [OsBr(eta (C5Me5)-C-5)(PiPr(3))] has been synthesized and structurally characterized. This unsaturated complex binds N-2 reversibly at low temperature as determined by IR and multinuclear NMR spectroscopy. The reactions of the title complex with CO, H-2, PhSiH3, and its thermolysis in C6H6 are reported.

引用

页码：2747 / 2750

页数：4

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