Synthesis of Conjugated Donor-Acceptor Antiaromatic Porphyrins and Their Application to Perovskite Solar Cells

被引：9

作者：

Zheng, Xue-Lin ^{[1
,2
]}

Lin, Hao-Sheng ^{[3
,4
]}

Zhang, Bo-Wen ^{[4
]}

Maruyama, Shigeo ^{[4
]}

Matsuo, Yutaka ^{[1
,2
,3
,4
]}

机构：

[1] Univ Sci & Technol China, Sch Chem & Mat Sci, Dept Chem, Hefei 230026, Anhui, Peoples R China

[2] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China

[3] Nagoya Univ, Grad Sch Engn, Dept Chem Syst Engn, Nagoya, Aichi 4648603, Japan

[4] Univ Tokyo, Grad Sch Engn, Dept Mech Engn, Tokyo 1138656, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 87卷 / 09期

基金：

日本学术振兴会; 日本科学技术振兴机构;

关键词：

SMALL-MOLECULE; FULLERENE; EFFICIENT; RING;

D O I：

10.1021/acs.joc.1c01947

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A conjugated donor-acceptor antiaromatic porphyrin, composed of an antiaromatic thieno-fused porphyrin structure and a diketopyrrolopyrrole mioety, was synthesized and applied in a perovskite solar cell for the first time. Enhanced light absorption in the device by the antiaromatic porphyrin resulted in a significantly increased power conversion efficiency of 19.3%.

引用

页码：5457 / 5463

页数：7

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