Synthesis, Structure and Characterization of Three Metal Molybdate Hydrates: Fe(H2O)2(MoO4)2•H3O, NaCo2(MoO4)2(H3O2) and Mn2(MoO4)3•2H3O

被引：0

作者：

Yu Yang ^{[1
]}

Liu Dan ^{[1
]}

Hu Wei-wei ^{[1
]}

Li Jia ^{[1
]}

Peng Yu ^{[1
]}

Zhou Qi ^{[1
]}

Yang Fen ^{[1
]}

Li Guang-hua ^{[1
]}

Shi Zhan ^{[1
]}

Feng Shou-hua ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2012年 / 28卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Mixed-solvent-thermal synthesis; Crystal structure; Transition metal molybdate; Magnetic property; CRYSTAL-STRUCTURE; ELECTRONIC-STRUCTURE; MAGNETIC-PROPERTIES; COBALT MOLYBDATE; MECHANISM; MOSSBAUER; BEHAVIOR; PROPANE; OXIDES; COMOO4;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three metal molybdate hydrates, Fe(H2O)(2)(MoO4)(2)center dot H3O(FeMo), NaCo2(MoO4)(2)(H3O2)(CoMo) and Mn-2(MoO4)(3).2H(3)O(MnMo), were synthesized by the mixed-solvent-thermal methods and characterized by single-crystal X-ray diffraction. X-Ray photoelectron spectroscopy and bond-valence sums were applied to confirming the valance of Fe, Co, Mn and Mo. Thermo-gravimetric analysis and X-ray powder diffraction measurements indicate that the samples were converted to different structural compounds upon heating in air at 600 degrees C for 1 h. The magnetic properties of these compounds were studied. The dominant magnetic interactions are antiferromagnetic in nature. However, different synthesis conditions led to the diversity of magnetic properties of compound CoMo.

引用

页码：186 / 190

页数：5

共 50 条

[41] CD3+ EPR IN KY(MOO4)2 AND KLU(MOO4)2
OTKO, AI
PELIKH, LN
FIZIKA TVERDOGO TELA, 1974, 16 (03): : 967 - 969
[42] Crystal structure of a new ternary molybdate in the Rb2MoO4-Eu2(MoO4)3-Hf(MoO4)2 system
Bazarov, B. G.
Chimitova, O. D.
Klevtsova, R. F.
Tushinova, Yu. L.
Glinskaya, L. A.
Bazarova, Zh. G.
JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 49 (01) : 53 - 57
[43] Crystal structure of a new ternary molybdate in the Rb2MoO4-Eu2(MoO4)3-Hf(MoO4)2 system
B. G. Bazarov
O. D. Chimitova
R. F. Klevtsova
Yu. L. Tushinova
L. A. Glinskaya
Zh. G. Bazarova
Journal of Structural Chemistry, 2008, 49 : 53 - 57
[44] Electric Conductivity of In2(MoO4)3 and Composites (1 – х)In2(MoO4)3–хMoO3
N. N. Pestereva
A. F. Guseva
Ya. A. Dahle
Russian Journal of Electrochemistry, 2021, 57 : 817 - 824
[45] Thermal stability of In2(MoO4)3 and phase equilibria in the MoO3-In2O3 system
Filipek, E.
Rychlowska-Himmel, I.
Paczesna, A.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2012, 109 (02) : 711 - 716
[46] Existence of Two Concomitant Magnetic Structures Below TNeel for the Natrochalcite, NaFe2II(H3O2)(MoO4)2
Maalej, Wassim
Vilminot, Serge
Andre, Gilles
Elaoud, Zakaria
Mhiri, Tahar
Kurmoo, Mohamedally
INORGANIC CHEMISTRY, 2011, 50 (18) : 9191 - 9199
[47] Synthesis and crystal structure of ammonium dimolybdatouranylate monohydrate (NH4)2[UO2(MoO4)2] • H2O
Andreev, GB
Antipin, MY
Fedoseev, AM
Budantseva, NA
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2001, 27 (03) : 208 - 210
[48] Synthesis and Crystal Structure of Ammonium Dimolybdatouranylate Monohydrate (NH4)2[UO2(MoO4)2] · H2O
G. B. Andreev
M. Yu. Antipin
A. M. Fedoseev
N. A. Budantseva
Russian Journal of Coordination Chemistry, 2001, 27 : 208 - 210
[49] Synthesis and crystal structure of ammonium dimolybdatouranylate monohydrate (NH4)2[UO2 (MoO4)2]·H2O
Andreev, G.B.
Antipin, M.Yu.
Fedoseev, A.M.
Budantseva, N.A.
Koordinatsionnaya Khimiya, 2001, 27 (03): : 227 - 231
[50] Extended frameworks encapsulating facial {MoO3} units:: Syntheses and structural characterizations of Ba3(MoO3)3(H2O)3(H2O)(AsO4)2, SrMoO3HAsO4•H2O, and Sr(MoO2AsO4)2
Hsu, KF
Wang, SL
CHEMISTRY OF MATERIALS, 1999, 11 (07) : 1876 - 1882

← 1 2 3 4 5 →