Three new pure antiferroelectric materials, synthesized at the Military University of Technology (MUT), were investigated by dielectric means. Clear relaxation modes were detected, i.e., Soft, Goldstone, low frequency in-phase (P-L) as well high frequency anti-phase (P-H) modes for paraelectric Sm A*phase, ferroelectric Sm C* phase and antiferroelectric Sm C-A* phase, respectively. Additionally, a high relaxation mode in Sm C-A* was found. The relaxation frequencies f(R) of the observed modes were calculated from Cole-Cole diagrams.