The isotropic temperature-dependent potential describing the binary interactions in gaseous WF6 and MoF6

被引:11
|
作者
Zarkova, L
Pirgov, P
机构
[1] Institute of Electronics, Sofia 1784, blvd Tzarigradsko Schaussee
关键词
D O I
10.1088/0953-4075/29/19/014
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The parameters of the temperature-dependent isotropic potentials of binary WF6-WF6 and MoF6-MoF6 interactions are obtained from the experimentally measured second virial coefficient B and viscosity eta of these gases. The parameters of the ground state (equilibrium distance r(m) and the potential depth well epsilon at T = 0 K, together with the repulsive parameter n and the temperature dependence r(m)((eff))(T)) are defined and can be used to calculate any potential-dependent property of the two gases. The measured viscosities of the WF6-UF6 and MoF6-UF6 mixtures at T = 354 K are reproduced within the experimental error using earlier defined potential parameters for UF6.
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页码:4411 / 4422
页数:12
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