Methanolysis of polycarbonate catalysed by ionic liquid [Bmim][Ac]

被引：103
|
作者：
Liu, Fusheng [1 ]
Li, Lei [1 ]
Yu, Shitao [1 ]
Lv, Zhiguo [1 ]
Ge, Xiaoping [1 ]
机构：
[1] Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao 266042, Peoples R China
来源：
JOURNAL OF HAZARDOUS MATERIALS | 2011年 / 189卷 / 1-2期
基金：
中国国家自然科学基金;
关键词：
Ionic liquid; Methanolysis; Polycarbonate; Recycling; BISPHENOL-A; DECOMPOSITION; DEGRADATION; KINETICS;
D O I：
10.1016/j.jhazmat.2011.02.032
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The methanolysis of polycarbonate (PC) was studied using ionic liquid [Bmim][Ac] as a catalyst. The effects of temperature, time, methanol dosage and [Bmim][Ac] dosage on the methanolysis reaction were examined. It was shown that the conversion of PC was nearly 100%, and the yield of bisphenol A (BPA) was over 95% under the following conditions: m([Bmim][Ac]):m(PC) = 0.75:1; m(methanol):m(PC) = 0.75:1; a reaction temperature of 90 degrees C and a total time of 2.5h. The ionic liquid could be reused up to 6 times with no apparent decrease in the conversion of PC and yield of BPA. The kinetics of the reaction was also investigated. The results indicated that the methanolysis of PC in [Bmim][Ac] was a first-order kinetic reaction with an activation energy of 167 kJ/mol. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：249 / 254
页数：6
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