Preparation and Fundamental Characterization of Cellulose Nanocrystal from Oil Palm Fronds Biomass

被引：40
|
作者：
Dungani, Rudi [1 ]
Owolabi, Abdulwahab F. [2 ,3 ]
Saurabh, Chaturbhuj K. [2 ]
Khalil, H. P. S. Abdul [2 ,4 ]
Tahir, Paridah M. [4 ]
Hazwan, C. I. C. M. [2 ]
Ajijolakewu, Kamoldeen A. [2 ,3 ,5 ]
Masri, M. M. [2 ]
Rosamah, E. [6 ]
Aditiawati, P. [1 ]
机构：
[1] Inst Teknol Bandung, Sch Life Sci & Technol, Gandung Labtex 11, Bandung, Indonesia
[2] Univ Sains Malaysia, Sch Ind Technol, George Town 11800, Malaysia
[3] Fed Inst Ind Res Oshodi, Lagos, Nigeria
[4] Univ Putra Malaysia, Lab Biocomposite Technol, Inst Trop Forestry & Forest Prod, Serdang, Malaysia
[5] Univ Ilorin, Dept Microbiol, Ilorin, Nigeria
[6] Mulawarman Univ, Fac Forestry, Campus Gunung Kelua, Samarinda 75119, East Kalimantan, Indonesia
来源：
JOURNAL OF POLYMERS AND THE ENVIRONMENT | 2017年 / 25卷 / 03期
关键词：
Nanocrystalline cellulose; Total chlorine free bleaching; Oil palm fronds; Thermal properties; X-ray diffraction; Fourier transform infrared spectroscopy; CHEMICAL-COMPOSITION; EXTRACTION; FIBERS; POLYSACCHARIDES; DELIGNIFICATION; PRETREATMENT; ALKALINE; CLEAVAGE; HUSK; PULP;
D O I：
10.1007/s10924-016-0854-8
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The objective of this work was to isolate cellulose nanocrystal (CNC) from oil palm fronds (Elaeis guineensis) and its subsequent characterization. Isolation involves sodium hydroxide/anthraquinone pulping with mechanical refining followed by total chlorine free bleaching (includes oxygen delignification, hydrogen peroxide oxidation and peracetic acid treatment) before acid hydrolysis. Bleaching significantly decreased kappa number and increased alpha-cellulose percentage of fibers as confirmed by Technical Association of the Pulp and Paper Industry standards. Transmission electron microscopy (TEM), X-ray diffraction, Fourier transform infrared spectroscopy and thermogravimetric analysis revealed that acid hydrolysis along with bleaching improved crystallinity index and thermal stability of the extracted nanocrystals. It was observed that CNC maintained its cellulose 1 polymorph despite hydrolysis treatment. Mean diameter as observed by TEM and average fiber aspect ratio of obtained CNC was 7.44 +/- 0.17 nm and 16.53 +/- 3.52, respectively making it suitable as a reinforcing material for nanocomposite.
引用
下载
收藏
页码：692 / 700
页数：9
相关论文
共 50 条
  • [21] CELLULOSE ACETATE PRODUCTION BY ACETYLATION OF CELLULOSE DERIVED FROM DATE PALM FRONDS
    Jassem, A. S.
    Muallah, Sh K.
    Mohammed, A. H.
    IRAQI JOURNAL OF AGRICULTURAL SCIENCES, 2020, 51 (03): : 967 - 975
  • [22] Properties of Cellulose Extract from Different Types of Oil Palm Biomass
    Megashah, L. N.
    Ariffin, H.
    Zakaria, M. R.
    Hassan, M. A.
    WOOD AND BIOFIBER INTERNATIONAL CONFERENCE (WOBIC 2017), 2018, 368
  • [23] A STUDY ON CELLULOSE FROM OIL PALM BIOMASS AS A SOURCE OF BIOETHANOL PRODUCTION
    Sitinjak, Elvri Melliaty
    Masmur, Indra
    Sitanggang, Yenny
    Pratikha, Rycce Sylviana
    Nainggolan, Fernando
    Yatasya, Fauzatu Arabica
    Afandi, Trisno
    Tarigan, Krissandarta
    Hutajulu, Poltak Evencus
    Destty, New Vita Mey
    Gultom, Golfrid
    CELLULOSE CHEMISTRY AND TECHNOLOGY, 2023, 57 (3-4): : 369 - 375
  • [24] Preparation and Characterization of Cellulose Microcrystalline (MCC) from Fiber of Empty Fruit Bunch Palm Oil
    Nasution, H.
    Yurnaliza
    Veronicha
    Irmadani
    Sitompul, S.
    1ST ANNUAL APPLIED SCIENCE AND ENGINEERING CONFERENCE (AASEC), IN CONJUCTION WITH THE INTERNATIONAL CONFERENCE ON SPORT SCIENCE, HEALTH, AND PHYSICAL EDUCATION (ICSSHPE), 2017, 180
  • [25] Cellulose Nanocrystal (CNC) Capsules from Oil Palm Empty Fruit Bunches (OPEFB)
    Soetaredjo, Felycia Edi
    Santoso, Sheila Permatasari
    Waworuntu, Gladdy L.
    Darsono, Farida Laniwati
    BIOINTERFACE RESEARCH IN APPLIED CHEMISTRY, 2022, 12 (02): : 2013 - 2021
  • [26] Preparation, characterization and acetylation of cellulose nanocrystal allomorphs
    Zhenhua Wu
    Jun Xu
    Jie Gong
    Jun Li
    Lihuan Mo
    Cellulose, 2018, 25 : 4905 - 4918
  • [27] Preparation, characterization and acetylation of cellulose nanocrystal allomorphs
    Wu, Zhenhua
    Xu, Jun
    Gong, Jie
    Li, Jun
    Mo, Lihuan
    CELLULOSE, 2018, 25 (09) : 4905 - 4918
  • [28] Intensive exploration of the fuel characteristics of biomass and biochar from oil palm trunk and oil palm fronds for supporting increasing demand of solid biofuels in Thailand
    Kongto, Pumin
    Palamanit, Arkom
    Ninduangdee, Pichet
    Singh, Yashvir
    Chanakaewsomboon, Issara
    Hayat, Asif
    Wae-hayee, Makata
    ENERGY REPORTS, 2022, 8 : 5640 - 5652
  • [29] Cellulose nanofibers of oil palm fronds as a filler in nanocomposite coating for corrosion protection of copper
    Randis, Randis
    Darmadi, Djarot B.
    Gapsari, Femiana
    Sonief, Achmad As'Ad
    Anam, Khairul
    Lai, Chin Wei
    INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2024, 279
  • [30] Elemental and Thermo-Chemical Analysis of Oil Palm Fronds for Biomass Energy Conversion
    Guangul, Fiseha Mekonnen
    Sulaiman, Shaharin Anwar
    Raghavan, Vijay R.
    4TH INTERNATIONAL MEETING OF ADVANCES IN THERMOFLUIDS (IMAT 2011), PT 1 AND 2, 2012, 1440 : 1197 - 1205
12345