8-Hydroxy-2-methylquinolinium diiodido(2-methylquinolin-8-olato-κ2N,O)zincate(II) methanol monosolvate

被引：3
|
作者：
Najafi, Ezzatollah [2 ]
Amini, Mostafa M. [2 ]
Ng, Seik Weng [1 ]
机构：
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
D O I：
10.1107/S1600536810036718
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The anion of the title salt, (C10H10NO)[Zn(C10H8NO)I-2]center dot-CH3OH, has its metal atom N,O-chelated by the deprotonated 2-methyl-8-hydroxyquinoline ligand. The hydroxy unit of the cation is a hydrogen-bond donor to the alkoxide O atom of the tetrahedrally coordinated anion, whereas the ammonium cation acts as a hydrogen-bond donor to the methanolic O atom. In the crystal, adjacent ion pairs and solvent molecules are linked by a methanol-halogen O-H center dot center dot center dot I hydrogen bond, generating a chain running along the a axis.
引用
收藏
页码：M1277 / U1014
页数：9
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